The similarity between the atomic volumes of the dhcp Pr and the hypothetical fce Pr phases and the disappearance of the dhcp fee transition in the Pr Ce alloys containing more than 90 at.% Pr have indicated the possibility that there is a delicate relationship in favour of the dhcp phase towards the praseodymium end. The observed positive deviation from the line connecting the atomic volumes of the dhcp Pr and dhcp Ce has been attributed to the change of the effective valency of cerium from 3.1 to 3. A tentative phase diagram for the Pr Ce system has been presented which is similar to the La Nd phase diagram proposed by Gschneidner (1961)..

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